Springer Online Journal Archives 1860-2000
Chemistry and Pharmacology
Energy, Environment Protection, Nuclear Power Engineering
Abstract A new procedure for the radiochemical measurements of thorium, uranium and plutonium in atmospheric samples is described. Analysis involves coprecipitation of these actinides with iron hydroxide from a 40-to 50-dm3 sample of rainwater, followed by radiochemical separation and purification procedures by the use of ion exchange chromatography (Dowex AG1×8) and solvent extraction. The new procedure enables one to determine the isotopes of thorium, uranium and plutonium, which are found in rainwater at extremely low concentrations, with a chemical yield ranging from 60 to 80%.
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