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  • 1
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The fracture behavior of a piperidine/bisphenol A diglycidyl ether (A) resin has been determined in bulk and as an adhesive using the linear elastic fracture methods developed by Mostovoy1. The effect of adding carboxy-terminated butadiene-acrylonitrile (CTBN) elastomer to resin A was investigated. The opening-mode fracture energy () of resin A was 120 to 150 J/m2, and largely attributable to plastic deformation. Fractographic evidence was obtained for plastic flow at the crack tip during crack initiation. Propagation was unstable due to the rate dependence of the plasticity. There were no significant differences in the bulk and adhesive fracture behavior. Addition of 5-15% CTBN to resin A produced minute elastomer particles which increased to ∼4000J/m2 (at 15%). Further CTBN addition resulted in an elastomer-epoxy blend and a decrease in fracture energy. Fractography again indicated that crack initiation involved plastic deformation but that the elastomer had greatly increased the volume in which the deformation occurred. The adhesive fracture of the elastomer-epoxy was found to be strongly dependent on the crack-tip deformation zone size (ryc) in that was a maximum when bond thickness was equal to 2 ryc. At bond thicknesses less than 2 ryc, there was a restraint on the development of the plastic zone resulting in lower values.
    Additional Material: 13 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 18 (1974), S. 1261-1264 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Additional Material: 4 Tab.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 21 (1977), S. 2359-2373 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The kinetic parameters of the polymerization of diglycidyl ether of bisphenol A with hexahydrophthalic anhydride and benzyldimethylamine as catalyst were determined using differential scanning calorimetry. The reaction was found to be first order with some variation with temperature, and the activation energy and natural log of the frequency factor were 25 kcal/mole and ∼25 sec-1, respectively. These results are discussed with respect to a steady-state mechanism of the polymerization and compared with results reported for other epoxide-anhydride reactions.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
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