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  • 1
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: The preparation and properties of the following ternary sulfides and selenides of the general composition A2M3X4 are reported: K2Ni3S4, Rb2Ni3S4, Cs2Ni3S4; K2Ni3Se4; K2Pd3S4, Rb2Pd3S4, Cs2Pd3S4; K2Pd3Se4, Rb2Pd3Se4, Cs2Pd3Se4.All compounds are essentially non-magnetic, which indicates a planar sulphur coordination of Ni2+ and Pd2+. Investigations of the structure of Cs2Pd3S4 confirm this assumption.
    Notes: Es wird über Darstellung und Eigenschaften folgender ternärer Sulfide und Selenide mit der allgemeinen Zusammensetzung A2M3X4 berichtet: K2Ni3S4, Rb2Ni3S4, Cs2Ni3S4; K2Ni3Se4; K2Pd3S4, Rb2Pd3S4, Cs2Pd3S4; K2Pd3Se4, Rb2Pd3Se4, Cs2Pd3Se4.Alle Verbindungen sind nahezu unmagnetisch, was auf planare Schwefelkoordination von Ni2+ und Pd2+ hindeutet. Untersuchungen zur Struktur von Cs2Pd3S4 bestätigen diese Annahme.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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