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  • 1
    ISSN: 1572-879X
    Keywords: Iridium catalyst ; supported catalyst ; vapor-phase carbonylation ; methanol carbonylation ; active carbon support
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract Iridium on active carbon (Ir/A.C.) is an effective catalyst for the vapor-phase carbonylation of methanol. In contrast to rhodium-catalysts the reaction rate is nearly independent of the partial pressure of the methyl iodide promoter and the methanolysis of an iridium-acetyl species has been found to determine the rate. Undesired methane formation accompanying the carbonylation is suggested to proceed via proteolysis of iridium-methyl species by methanol or water. Methyl chloride has been found to be a less effective promoter than methyl iodide.
    Type of Medium: Electronic Resource
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