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  • Chemistry  (1)
  • Dextran-modified poly(methyl methacrylate) latex particles  (1)
  • charge neutralization
  • (Acremonian)
  • 1995-1999  (2)
  • 1999  (1)
  • 1995  (1)
  • 1995-1999  (2)
  • 1999  (1)
  • 1995  (1)
  • 1998  (1)
  • 1
    ISSN: 0142-2421
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Physics
    Notes: Thin (750 Å) plasma-polymerized films of acetylene were deposited onto polished steel substrates in an inductively coupled r.f. reactor. The films were characterized by x-ray photoelectron spectroscopy (XPS), Fourier-transform infrared spectroscopy (FTIR), Auger electron spectroscopy (AES) and secondary ion mass spectrometry (SIMS) immediately after deposition and after aging in the atmosphere. The FTIR spectra of the as-deposited films were characterized by bands related to mono- and disubstituted acetylene groups and by bands related to methyl and methylene groups. During exposure to the atmosphere, bands related to acetylenic groups decreased in intensity while new bands due to carbonyl groups appeared. When XPS spectra were obtained from films that were exposed to the atmosphere, new components assigned to oxidation products were observed in the C 1s spectra that were not observed for as-deposited films, verifying that oxidation had occurred. Numerous peaks related to aromatic structures were observed in positive SIMS spectra of as-deposited films. Results obtained from AES showed that the plasma-polymerized films were continuous and that the oxide on the substrate surface was partially reduced during deposition.Plasma-polymerized acetylene films were excellent primers for rubber-to-steel bonding. Miniature lap joints were prepared by using rubber as an ‘adhesive’ to bond together pairs of polished steel adherends primed with plasma-polymerized acetylene films. The force required to break the as-prepared joints was ∼2000 N for a bonded area of 64 mm2 and failure was 100% cohesive in the rubber. Similar results were obtained for joints prepared using polished brass substrates.Because of the complexity of reactions between rubber and the plasma-polymerized primer, a model ‘rubber’ consisting of a mixture of squalene, zinc oxide, carbon black, sulfur, stearic acid, cobalt naphthenate, N,N-dicyclohexylbenzothiazole sulfenamide and diaryl-p-diphenyleneamine was used to simulate the cross-linking reaction. The results obtained using XPS, SIMS, AES and FTIR showed that sulfur diffused through the primer to form a layer of sulfide at the primer/substrate interface. Zinc and cobalt sulfides and perthiomercaptides, which formed at the interface between squalene and the plasma-polymerized acetylene primer, catalyzed the reaction between squalene and the primer. Cross-links between squalene and the primer were mostly mono-sulfidic, although some evidence for di- and trisulfidic cross-links was observed.
    Additional Material: 17 Ill.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1435-1536
    Keywords: Key words Isothermal equilibrium adsorption ; Concanavalin A ; Dextran-modified poly(methyl methacrylate) latex particles ; Electrostatic/affinity interactions
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract Isothermal equilibrium adsorption experiments were carried out to study the adsorption of concanavalin A (Con A) on dextran-modified poly(methyl methacrylate) (PMMA) latex particles. Three PMMA particles with various levels of dextran modification were selected for study: 0% (designated as D0), 1.24% (D20), and 2.45% (D75) based on total polymer weight. The Langmuir model is applicable to both D0 and D20 systems, although the data for the D20 system are somewhat scattered. On the other hand, the amount of Con A adsorbed per gram polymer particles (q*) versus the Con A concentration in water (c*) curve for the D75 system cannot be described by the Langmuir model. The deviation is attributed to the formation of a crosslinked network structure, caused by specific binding of the dimeric Con A molecules onto two neighboring particles with grafted dextran. The ratio of the initial number of Con A molecules to the initial number of active binding sites on the dextran-modified particle surface plays an important role in determining the structure of flocs formed. The maximum amount of Con A adsorbed on the particle surface (q max) is of the order of 10−1 μmol per gram particles and q max in decreasing order is D75 〉 D20 〉 D0. The dissociation constant of the Con A-D20 (or Con A-D75) pair is of the order of 10−1 μmol dm−3 which is 1 order of magnitude smaller than that of the Con A-D0 pair. Thus, the electrostatic interaction between Con A and D0 is much weaker than the affinity interaction between Con A and D20 (or D75). An empirical model is proposed to qualitatively explain the q* versus c* data.
    Type of Medium: Electronic Resource
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