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  • 1
    ISSN: 0044-2313
    Keywords: Mono-, di-, and trinuclear tantalum and tantalum | niobium complexes with P4 and P2 ligands ; m̈-η2:1:1-P2 coordination mode ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Niobium and Tantalum Complexes with P2 and P4 LigandsThe photolysis of [Cp″Ta(CO)4] 1 (Cp″ = C5H3tBu2-1,3) and P4 affords Cp″(CO)2Ta(η4-P4) 2, [{Cp″(CO)Ta}2(m̈-η2:2-P2)2] 3 and [Cp3″(CO)3Ta3(P2)2] 4. In a photochemical reaction 2 and [Cp*Nb(CO)4] 5 form [{Cp*(CO)Nb}{Cp″(CO)Ta}(m̈-η2:2-P2)2] 6 and [{Cp*(CO)2Nb} {Cp*Nb}{Cp″(CO)Ta}(m̈3-η2:1:1-P2)2] 7, a compound with the novel m̈3-η2:2:1-P2-coordination mode. The reaction of 2 and [Cp*Co(C2H4)2] 8 leads to [{Cp*Co} {Cp″(CO)Ta}(m̈-η2:2-P2)2] 9, a heteronuclear complex with an „early“ and a „late“ transition metal. Complexes 2, 3, 7 and 9 have been further characterized by X-ray structure analyses.
    Notes: Die Photolyse von [Cp″Ta(CO)4] 1 (Cp″ = C5H3tBu2-1,3) und P4 ergibt [Cp″(CO)2Ta(η4-P4)] 2, [{Cp″(CO)Ta}2(μ-η2:2-P2)2] 3 und [Cp3″(CO)3Ta3(P2)2] 4. 2 reagiert photochemisch mit [Cp*Nb(CO)4] 5 zu [{Cp*(CO)Nb}{Cp″(CO)Ta}(m̈-η2:2-P2)2] 6 und [{Cp*(CO)2Nb}{Cp*Nb} {Cp″(CO)Ta}(m̈3-η2:1:1-P2)2] 7, einer Verbindung mit der neuen m̈3-η2:2:1-P2-Koordinationsvariante. Die Reaktion von 2 und [Cp*Co(C2H4)2] 8 führt zum heteronuklearen Komplex [{Cp*Co} {Cp″(CO)Ta}(m̈-η2:2-P2)2] 9 mit einem „frühen“ und „späten“ Übergangsmetall. Die Komplexe 2, 3, 7 und 9 wurden zusätzlich durch eine Röntgenstrukturanalyse charakterisiert.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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