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  • Polymer and Materials Science  (8)
  • 1
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    ISSN: 0449-2978
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: NMR linewidth studies of molecular motion in several polyacrylonitrile samples have been carried out. The motional transition temperature is found in the 105-124°C. range and depends upon polymerization conditions. In addition, the thermal activation energy for the motional process underlying this transition was evaluated at 16.4 kcal./mole. Finally, measurement of the transition temperature for one of the specimens in three different physical states (bulk, spun only, and spun and drawn with a ratio of 3:1), revealed that no change in the transition temperature was effected by either spinning or drawing.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    ISSN: 0449-2978
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Wideline NMR techniques have been applied to both singly and doubly oriented specimens of nylon 66. Variations in the spectra obtained are observed for different orientations of the specimens relative to the applied field. These variations demonstrate that the zigzag chain axis is essentially parallel to the draw direction and that motion occurs in all of the sample. The motion is of two types: random in the mobile regions and rotation of segments about the chain axis in the rigid regions.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    ISSN: 0449-2978
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: NMR linewidth studies of nylon 66 as a function of temperature and applied tensile stress have been conducted. The principal motional transition temperature was found to be shifted to higher temperatures with stress application by 9°C./g./den. At any given temperature, increased stress resulted in an increased linewidth. An attempt was made to correlate the shift in the motional transition temperature with the concept that a segment experiencing motion must do work against the applied tensile stress.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    ISSN: 0449-2986
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    ISSN: 0449-2986
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 31 (1986), S. 965-977 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Liquid crystal polymers (LCP) have been developed for the first time as a thermoplastic matrix for high-performance composites. A successful melt impregnation method has been developed that results in the production of continuous carbon fiber (CF)-reinforced LCP prepreg tape. Subsequent layup and molding of prepreg into laminates has yielded composites of good quality.Tensile and flexural properties of LCP-CF composites are comparable to those of epoxy-CF composites. LCP-CF composites have better impact resistance than the latter, although epoxy-CF composites possess superior compression and shear strength. LCP-CF composites have good property retention until 200°F (67% of room temperature value). Above 200°F, mechanical properties are found to decrease significantly. Experimental results indicate that the poor compression and shear strength may be due to the poor interfacial adhesion between the matrix and carbon fiber.
    Additional Material: 11 Ill.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 32 (1986), S. 5245-5245 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Type of Medium: Electronic Resource
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  • 8
    ISSN: 0021-9304
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Medicine , Technology
    Notes: A series of DL-methionine/L-leucine copolymers was prepared from the coresponding N-carboxy-anhydrides. The copolymers formed clear flexible films having low water vapor transmission rates. Peroxide oxidation of the pendant methyl-theioethyl groups to methyl-sulfinoethyl groups enhanced the hydrophilic properties of the membranes, and the water vapor transmission rates rapidly increased with an increase in the number of pendant methyl-sulfinoethyl groups. Increasing the leucine content of the membranes produced a 13-fold increase in the carbon dioxide permeability and a 6-fold increase in oxygen permeability, whereas, an increase in the methionine content doubled the carbon dioxide-oxygen separation factor.Synthetic poly (α-amino acids) are very similar to naturally occurring proteins with respect to composition and conformation. Because of these similarities, they are being considered in aerosol spray bandages, synthetic skin applications and as coatings for plastic prostheses. The unusual permeability characteristics of the DL-methionine/L-leucine copolymers make them interesting membranes for possible use in artificial kidney machines and blood oxygenators.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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