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  • 1
    ISSN: 0044-2313
    Keywords: Potassium ; Barium ; Cadmium ; Vanadium Oxide ; Crystal Structure ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: On an Alkali Alkaline-Earth Cadmium Oxovanadate: KBaCd2(VO4)(V2O7)Single crystals of KBaCd2(VO4)(V2O7) have been prepared by crystallization from melts. X-ray investigations led to monoclinic symmetry, space group C2h5—P21/n, a = 10.359(3), b = 6.986(2), c = 15.331(3) Å, β = 94.77(2), Z = 4. The hitherto unknown compound represents a new structure type and is one of those few examples containing VO4 and V2O7 groups.
    Notes: Einkristalle von KBaCd2(VO4)(V2O7) wurden durch Kristallisation aus der Schmelze erhalten. Röntgenographische Untersuchungen führten zu monokliner Symmetrie, Raumgruppe C2h5 — P21/n, mit a = 10,359(3), b = 6,986(2), c = 15,331(3), β = 94,77(2)°, Z = 4. Die bisher unbekannte Substanz vertritt einen neuen Strukturtyp und ist eines der wenigen Beispiele mit VO4- und V2O7-Baugruppen.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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