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  • 1
    ISSN: 1572-8951
    Keywords: Electron magnetic resonance ; EPR ; ENDOR ; ESE ; ESEEM ; aromatic radicals ; nitroaromatics ; thiophenes ; metal oxide surfaces ; alumina ; silica-alumina ; silica ; magnesia ; titania ; powder lineshape ; orientation selection ; exact cancellation ; EPR simulation ; ENDOR simulation ; ESEEM simulation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract Multi-frequency electron magnetic resonance (EMR) methods provide a powerful approach to the study of radicals adsorbed on metal oxide surfaces. The structure, adsorption characteristics, surface environment, and mobility of surface species often can be determined. In this review, EMR studies of radicals produced on oxide surfaces from polynuclear aromatic hydrocarbons, nitroaromatics, and sulfur-containing aromatics are considered. Intra- and intermolecular spin interactions are probed by techniques which emphasize Zeeman or non-Zeeman interactions, and couplings between unpaired electrons and nuclei such as1H,14N,17O,25Mg, and27Al are discussed.
    Type of Medium: Electronic Resource
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