Wiley InterScience Backfile Collection 1832-2000
Chemistry and Pharmacology
The synthesis and 119mSn Mössbauer spectra of a series of 12 new and 3 other organotin complexes of general structure (4-ZC6H4)2SnCl2.L2.(Z = CH3, CF3, F, Cl, OCH3, L2=2,2′-bipyridyl, 1,10-phenanthroline, 2-aminomethylpyridine) arereported. A convenient method for the preparation of the intermediate diaryltin(IV) dihalides is given. The complexes fall into two isomeric types with either a trans- or cis-[ArSnAr] geometry. For this series 2-aminomethylpyridine gives exclusively the cis-[ArSnAr] geometry in its complexes.
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