Springer Online Journal Archives 1860-2000
Chemistry and Pharmacology
Conclusions 1. We have studied the telomerization of alkane- and arenesulfamides with linear and cyclic 1,3-dienes in the presence of a palladium catalyst system, Pd(acac)2-PPh3-AlEt3; high-molecular-weight N-substituted unsaturated sulfamides, difficult to prepare by other means, are obtained. 2. Introduction of bulky substituents to the N atom of alkanesulfamides drastically reduces their reactivity toward 1,3-dienes.
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