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  • 1
    ISSN: 0075-4617
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Reaction of Aminoaroxyls with Triarylphosphines, I.  -  A Simple Method for the Preparation of o-Hydroxyphosphine Imines2-Amino-4,6-dialkylphenols (e. g. 1) in ethanolic solution are oxidized by air to the corresponding phenoxyls 2. These radicals react smoothly with triarylphosphines to give the o-hydroxyphosphine imines 3. The properties of the new compounds and the course of reaction are described.
    Notes: 2-Amino-4.6-dialkyl-phenole (z. B. 1) werden in äthanolischer Lösung durch Luftsauerstoff in die entsprechenden Phenoxyle 2 übergeführt. Diese Radikale reagieren mit tertiären aromatischen Phosphinen in guten Ausbeuten zu den o-Hydroxy-phosphiniminen 3. Die Eigenschaften der neuen Verbindungen und der Reaktionsweg werden beschrieben.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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