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  • 1
    ISSN: 0170-2041
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Reactions of Cyanide Ions with α,β-Unsaturated Esters, V1). - Reactions Leading to Affiliation of CarbocyclesSodium cyanide reacts with the unsaturated diesters 4-6 under aprotic conditions (DMSO) to give the bicycles 7-9. These are easily transformed into the acids 10-12 and the methyl esters 13-15. Reaction with unsaturated esters like 16, 18 leads to the bicyclic compounds with bridged atoms 17, 19.
    Notes: Natriumcyanid reagiert mit den ungesättigten Di-Estern 4-6 unter aprotischen Bedingungen (DMSO) zu den Bicyclen 7-9. Diese lassen sich leicht in die Säuren 10-12 sowie in die Ester 13-15 überführen. Bei Verwendung von ungesättigten Estern des Typs 16, 18 entstehen bicyclische Verbindungen mit Brückenkohlenstoffatomen 17, 19.
    Type of Medium: Electronic Resource
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