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  • 1
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Dihalogeno-bis-thioharnstoff-zink-Komplexe wurden mit einer Reihe von N-Donorliganden in Lösung umgesetzt. Folgende Neutralkomplexe, von denen einige Beispiele für Fünferkoordination des Zinks sind, wurden dabei charakterisiert: Zntu2Br2L2 mit tu = Thioharnstoff und L = 3-Methyl-, 4-Methyl-, 4-Vinylpyridin und Isochinolin; ZntuBr2L2 mit L = Chinolin und Isochinolin; Zntu2I2L mit L = 4-Methylpyridin; Zntu2Cl2L mit L = Isochinolin.
    Notes: Dihalo bis-thiourea zinc(II) complexes were reacted with a variety of ligands containing nitrogen donor atoms in a mixed solvent medium. The following mixed ligand complexes were characterised:[Zntu2Br2L2]0 where L = 3-methyl, 4-methyl, 4-vinyl pyridine and isoquinoline; [ZntuBr2L2]0 where L = quinoline and 2-methyl quinoline; [Zntu2I2L]0 where L = 4-methyl pyridine and [Zntu2Cl2L]0 where L = isoquinoline. All are non-electrolytic complexes and some of them are examples for less common penta-coordination.
    Additional Material: 3 Tab.
    Type of Medium: Electronic Resource
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