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  • 1
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: By electrolytical reduction of solutions of TiCl4 in methanol blue solutions of TiCl3 were obtained from which the crystalline adducts TiCl3 · 4 CH3OH and TiCl3 · 5 CH3OH were isolated. These solids were used as starting material for the preparation of other TiCl3 complexes. By exchange of ligands blue TiCl3 · 3 DMF was obtained which in vacuo could be thermally decomposed to green TiCl3 · 2 DMF. The thermal decomposition of TiCl3 · 3 THF was newly studied. Magnetic susceptibilities, infrared and electron spectra were measured.
    Notes: Durch elektrolytische Reduktion von TiCl4 in Methanol wurden blaue TiCl3-Lösungen erhalten, aus denen die kristallinen Addukte TiCl3 · 4 CH3OH und TiCl3 · 5 CH3OH isoliert werden konnten. Diese dienten als Ausgangsmaterial zur Präparation anderer TiCl3-Komplexe. Durch Ligandenaustausch wurde blaues TiCl3 · 3 DMF erhalten, das sich im Vakuum thermisch zu grünem TiCl3 · 2 DMF abbauen ließ (DMF = Dimethylformamid). Der thermische Abbau von TiCl3 · 3 THF wurde neu untersucht. Magnetische Suszeptibilitäten, Infrarot- und Elektronenspektren wurden gemessen.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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