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  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 373 (1970), S. 182-188 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: By the reduction of C3F7Fe(CO)4J with sodium borohydride in methanol a solution is obtained from which derivatives of the very unstable perfluoropropyliron tetracarbonyl hydride C3F7Fe(CO)4H can be precipitated. The compounds [C3F7Fe(CO)4]2Hg and [C3F7Fe(CO)4]2[Fe(N2C12H8)3] have been characterized by their IR, NMR and mass spectra.
    Notes: Durch Reduktion einer Lösung von Heptafluor-n-propyl-eisen-tetracarbonyljodid, C3F7Fe(CO)4J, in Methanol mittels Natriumboranats entsteht eine Lösung, aus der Quecksilbercyanid und Tri-o-phenanthrolin-eisen(II)-sulfat Derivate des Heptafluor-n-propyl-eisentetracarbonylwasserstoffs, [C3F7Fe(CO)4]2Hg und [C3F7Fe(CO)(4)]2[Fe(N2C12H8)3] ausfällen. Aus dem Phenanthrolinderivat kann mittels Phosphorsäure das äußerst zersetzliche Carbonylhydrid C3F7Fe(CO)4H in Freiheit gesetzt werden. Die beiden beständigen Verbindungen sind durch IR-, NMR- und Massenspektren charakterisiert worden.
    Additional Material: 3 Tab.
    Type of Medium: Electronic Resource
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