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  • 1
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Crystal Structure of Tetracäsium-μ-oxo-decachlordiosmate(IV), Cs4[Os2OCl10]The anhydrous binuclear complex Cs4[Os2OCl10] crystallizes with an orthorhombic unit cell, Pcab, a = 12.521, b = 13.994, c = 11.798 Å and Z = 4 formula units. The complex anion forms corner sharing octahedrons tetragonally deformed. The interatomic distances are Os — O = 1.778 Å and Os — Cl = 2.370 (4×) and 2.433 Å (1×) respectively. The Cs atoms are coordinated differently. The interatomic distances Cs — Cl range from 3.46 to 3.87 Å. The structure is discussed in connection with analogous complexes. Details of other polynuclear complexes of Os are added.
    Notes: Der wasserfreie Zweikernkomplex Cs4[Os2OCl10] kristallisiert orthorhombisch in Pcab mit a = 12,521 Å, b = 13,994 Å, c = 11,798 und Z = 4 Formeleinheiten. Die komplexen Anionen bilden gestreckte, eckenverknüpfte Oktaeder mit Sauerstoff als Brückenatom. Die Bindungsabstände betragen Os — O = l,778 Å und Os — Cl = 2,370 Å (4×) bzw. 2,433 Å (1×). Die Cs-Atonie sind unterschiedlich koordiniert. Die Abstände Cs — Cl liegen im Bereich von 3,46 bis 3,87 Å. Die Struktur wird im Zusammenhang mit analogen Komplexen diskutiert. Es werden Angaben zu weiteren Mehrkernkomplexen des Os gemacht.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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