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  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 545 (1987), S. 43-46 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Rutile-Type Structure with Chains of Tetrahedra: The Compound CaCu4P2CaCu4P2 was prepared by heating the elements (slight excess of Cu, 850-950°C) and investigated by single crystal X-ray methods. The compound crystallizes tetragonally in a rutile-type structure (P42/mnm, a = 729.0(2) pm, c = 383.1(1) pm) built up by Ca and P atoms in which Cu atoms occupy the vacancies in form of chains of edge-shared tetrahedra.
    Notes: CaCu4P2 wurde aus den Elementen dargestellt (geringer Cu-Überschuß, 850-950°C) und röntgenographisch mit Einkristallmethoden untersucht. Die Verbindung kristallisiert tetragonal (P42/mnm, a = 729, 0(2) pm, c = 383, 1(1) pm) in einer von Ca- und P-Atomen aufgebauten Rutilstruktur, bei welcher Cu-Atome in Form kantenverknüpfter Tetraederketten die noch freien Plätze besetzen.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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