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  • 1
    ISSN: 0044-2313
    Keywords: Tetramethyltitanium complexes ; n.m.r. data ; MO calculations ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Contributions to the Chemistry of Transition Metal Alkyl Compounds. 62. Preparation and NMR-spectroscopic Characterization of Tetramethyltitanium ComplexesComplexes of tetramethyltitanium with THF and oxygen, nitrogen and phosphorous containing chelating ligands were synthesized and characterized by low temperature n.m.r. spectroscopy. The obtained complexes show a dynamic behaviour in solutions. The results of semiempirical MO calculations favour octahedral and not a trigonal prismatic configuration of the complexes.
    Notes: Komplexe des Tetramethyltitans mit THF, sowie sauerstoff-, stickstoff- und phosphorhaltigen Chelatliganden wurden synthetisiert und 1H- und 13C-NMR-spektroskopisch bei tiefen Temperaturen charakterisiert. Die erhaltenen Komplexe zeigen in Lösung ein dynamisches Verhalten. Aufgrund semiempirischer MO-Berechnungen ist einer oktaedrischen Konfiguration der Vorrang gegenüber einem trigonal-prismatischem Aufbau einzuräumen.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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