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  • 1
    ISSN: 0894-3230
    Keywords: Organic Chemistry ; Physical Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The reaction which forms hydroxymethylbenzodioxane from epibromohydrin and catecholate anion was examined by ultraviolet spectroscopy for the kinetics and by proton nuclear magnetic resonance spectroscopy to follow the fate of CD2 from reactant to product. Over the practical temperature range it was found that both CH2 positions in the epihalohydrin are attacked by catecholate anion to give product. Therefore, the difference in energy for the two pathways was small. The individual rate constants were obtained from the total rate constants. Further, the individual ΔH
    Additional Material: 4 Tab.
    Type of Medium: Electronic Resource
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