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  • 1
    ISSN: 0894-3230
    Keywords: Organic Chemistry ; Physical Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The bisporphyria N,N′-bis[4″-(meso-triphenylporphyrinyl)benzyl]-4,13-diaza-18-crown-6 and its mono- and dizinc derivatives were synthesized in 66%, 46% and 53% yields, respectively, from 5-(4′-bromomethylphenyl)-10,15,20-triphenylporphyrin or its zinc derivative and 4,13-diaza-18-crown-6. The zinc-containing bisporphyrins form dimers in solution at low temperature or at high concentration. The unsymmetrical bisporphyrin; monozinc N,N′-bis[4″-(meso-triphenylporphyrinyl)benzyl]-4,13-diaza-18-crown-6 shows singlet-singlet energy transfer from the zinc porphyrin moiety to the free base moiety in both the monomeric and the dimeric form. The energy transfer rates were determined using time-resolved fluorescence spectroscopy and were found to be 1·26 × 109 and 2·29 × 109 s-1 for the monomeric and dimeric form, respectively. The difference in energy transfer rates between the two forms can be rationalized by the difference in overlap between the donor fluorescence spectrum and acceptor absorption spectrum, donor-acceptor distance and donor-acceptor orientation.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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