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  • 1
    ISSN: 0887-624X
    Keywords: glycidyl vinyl ether ; carbon dioxide ; (2-oxo-1,3-dioxolan-4-yl) methyl vinyl ether ; cationic polymerization ; poly[(2-oxo-1,3-dioxolan-4-yl) methyl vinyl ether] ; radical copolymerization of OVE ; polymer reaction of P(OVE) ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: (2-Oxo-1,3-dioxolan-4-yl) methyl vinyl ether (OVE) was synthesized with high yield by addition reaction of glycidyl vinyl ether with carbon dioxide using tetrabutylammonium bromide (TBAB) as a catalyst. OVE was also prepared by reaction with β-butyrolactone or sodium hydrogencarbonate in the presence of TBAB as the catalyst. Poly [(2-oxo-1,3-dioxolan-4-yl) methyl vinyl ether] [P(OVE)] was obtained with high yield by cationic polymerization of OVE catalyzed using boron trifluoride diethyl ether complex in dichloromethane. Polymers bearing pendant 5-membered cyclic carbonate groups were also prepared by radical copolymerization of OVE with some electron-accepting monomers. Furthermore, addition reaction of P(OVE) with alkyl amines yielded the corresponding polymer having pendant 2-hydroxyethyl carbamate residue with high conversions. © 1994 John Wiley & Sons, Inc.
    Additional Material: 6 Tab.
    Type of Medium: Electronic Resource
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