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  • 1
    ISSN: 1434-4475
    Keywords: Keywords. Metal Silyl complexes; Oxidative addition; Hydride complexes.
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Zusammenfassung.  Photochemische Umsetzung von Cp′Mn(CO)3 mit HMe2Si-1,2-C6H4-SiMe2H und von Cp′Mn(CO)2PMe3 mit HMe2Si-X-SiMe2H (X=1,2-C6H4, C2H4,O) führt zur Bildung der oxidativen Additionsprodukte Cp′(CO)(L)Mn(H)SiMe2-X-SiMe2H. Außer bei der Kombination X= 1,2-C6H4 und L= PMe3 werden auch die zweikernigen Komplexe [Cp′(CO)(L)Mn(H)SiMe2]2 X gebildet.
    Notes: Summary.  The photochemical reaction of Cp′Mn(CO)3 with HMe2Si-1,2-C6H4-SiMe2H and of Cp′Mn(CO)2PMe3 with HMe2Si-X-SiMe2H (X=1,2-C6H4, C2H4, O) results in the formation of the oxidative addition products Cp′(CO)(L)Mn(H)SiMe2-X-SiMe2H. Except for the combination X= 1,2-C6H4 and L=PMe3, the binuclear complexes [Cp′(CO)(L)Mn(H)SiMe2]2 X are additionally formed.
    Type of Medium: Electronic Resource
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