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  • 1
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 88 (1988), S. 5553-5560 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: The effect of ion source pressure on the cross sections for photodissociation of SO+2 has been measured systematically at λirr =4735 and 4795 A(ring). Using a Stern–Volmer treatment modified to account for the dependence of source residence time on pressure, rate constants have been measured for quenching the A˜ 2A2 (v1,v2=3,3) and A˜ 2A2(v1,v2=3,0) states of SO+2 by N2O, SO2, CO2, and N2. With SO2 and N2O as quenchers the rate constants range between 1.0 and 6.5 times the theoretical thermal capture rate constants ("Langevin limit''). The occurrence of several resonant and many near-resonant charge transfer processes is proposed to explain the unusually large rate constants.
    Type of Medium: Electronic Resource
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